Does this come in navy blue and white, like the one daniel wore in the movies?

Yes, but it is not a nice thick cotton like the one from the movie. This one is more for show, it’s made of a very thin shiny polyester material. It slips and is NOT intended for actual sweat headband use.

What kind of fabric is this? Cotton? Polyester?

hiit is cotton / polyester mixture

How can i order mine in navy blue and white? ive seen photos that have the headbans in black and white but there is one review where it was navy blue

sorry we only have it in black and white

Would this work as a sweat band for active exercisingto prevent sweat dripping? Example, cycling, rowing, or indoor workout

I wish it would! That was the intention, however, it is made of a polyester that is spun to be silk like in texture and appreance. Extremely thin, non absorbing and, purely made for esthetics.